Abstract : Work aim to Synthesis electrolytic decoration of highly aromatic reduced cellulosic graphene (R5-R7), by preparing the diazonium salt, and adding the reduced Nano cellulose graphene (R4), to the ultrasonic device and then adding the amines, this solution was added to the electric cell that contains platinum electrodes with a voltage of 1.6 volts, This compounds were characterization and diagnosed by physical and spectroscopic methods, including melting point measurement, infrared spectroscopy (FT-IR), X-ray diffraction (XRD), electron microscopy (FESEM), atomic force microscopy (AFM), and thermo gravimetric analysis (TGA, DTG, DSC)of Some prepared Nano composites was measured, and The biological activity, which is known to be resistant to antibiotics, which are Staphylococcus aureus, gram-positive, and Escherichia coli, gram-negative.